Luminescence and a new approach for detecting heat treatment of geuda sapphire

Author(s)
Teerarat Pluthametwisute, Lutz Nasdala, Chutimun Chanmuang N., Manfred Wildner, Eugen Libowitzky, Gerald Giester, E. Gamini Zoysa, Chanenkant Jakkawanvibul, Waratchanok Suwanmanee, Tasnara Sripoonjan, Thanyaporn Tengchaisri, Bhuwadol Wanthanchaisaeng, Chakkaphan Sutthirat
Abstract

For decades, unraveling the heat treatment of sapphire has been a challenging issue. The present study offers new aspects that support the detection of heat treatment of sapphire. Natural geuda sapphire exhibits orange to red luminescence under longwave ultraviolet (LWUV; 365 nm) light, while heated geuda sapphire shows blue luminescence under shortwave ultraviolet (SWUV; 225 nm) light. The presence of melt inclusions in dissolved silks serves as an indicator of sapphire heat treatment. Fourier-transform infrared (FTIR) spectroscopy alone is insufficient for distinguishing unheated from heated sapphire. By combining orange to red luminescence with blue luminescence and melt inclusions, we provide a practical method for accurately differentiating natural gem-quality sapphire and heated gem-quality sapphire.

Organisation(s)
Department of Mineralogy and Crystallography
External organisation(s)
Chulalongkorn University, Mincraft Company, Gem and Jewelry Institute of Thailand, Chiang Mai University, Burapha University
Journal
Solid earth
Volume
16
Pages
81-96
No. of pages
16
ISSN
1869-9510
DOI
https://doi.org/10.5194/se-16-81-2025
Publication date
01-2025
Peer reviewed
Yes
Austrian Fields of Science 2012
105116 Mineralogy, 105113 Crystallography, 104026 Spectroscopy
Portal url
https://ucrisportal.univie.ac.at/en/publications/e0701c97-3545-4c3e-8f99-542c21ceb6e7