Superposition model analysis from polarized electronic absorption spectra of Co2+ in trigonally distorted octahedra in brucite-type Co(OH)2
- Author(s)
- Michael Andrut, Manfred Wildner
- Abstract
Temperature dependent polarized spectra and effective applicability of the superposition model (SM) concept to d-block element compounds were analyzed. The magnitude of the `correct' SM parameters of Co2+ for future application to structurally and/or chemically less defined systems was also discussed. It was observed that the specific position of closely related ligands within the spectrochemical series affects the intrinsic parameters.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Vienna
- Journal
- Journal of Physics: Condensed Matter
- Volume
- 13
- Pages
- 7353-7361
- No. of pages
- 9
- ISSN
- 0953-8984
- DOI
- https://doi.org/10.1088/0953-8984/13/33/315
- Publication date
- 2001
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 1051 Geology, Mineralogy
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/e4b90c60-c31f-4553-8eea-97a2c033e675