Addressing the complexity of water chemistry in environmental fate modeling for engineered nanoparticles
- Author(s)
- Nicole Sani-Kast, Scheringer Martin, Danielle Slomberg, Jérôme Labille, Antonia Praetorius, Patrick Ollivier, Konrad Hungerbühler
- Abstract
Engineered nanoparticle (ENP) fate models developed to date — aimed at predicting ENP concentration in the aqueous environment — have limited applicability because they employ constant environmental conditions along the modeled system or a highly specific environmental representation; both approaches do not show the effects of spatial and/or temporal variability. To address this conceptual gap, we developed a novel modeling strategy that: 1) incorporates spatial variability in environmental conditions in an existing ENP fate model; and 2) analyzes the effect of a wide range of randomly sampled environmental conditions (representing variations in water chemistry). This approach was employed to investigate the transport of nano-TiO2 in the Lower Rhône River (France) under numerous sets of environmental conditions. The predicted spatial concentration profiles of nano-TiO2 were then grouped according to their similarity by using cluster analysis. The analysis resulted in a small number of clusters representing groups of spatial concentration profiles. All clusters show nano-TiO2 accumulation in the sediment layer, supporting results from previous studies. Analysis of the characteristic features of each cluster demonstrated a strong association between the water conditions in regions close to the ENP emission source and the cluster membership of the corresponding spatial concentration profiles. In particular, water compositions favoring heteroaggregation between the ENPs and suspended particulate matter resulted in clusters of low variability. These conditions are, therefore, reliable predictors of the eventual fate of the modeled ENPs. The conclusions from this study are also valid for ENP fate in other large river systems. Our results, therefore, shift the focus of future modeling and experimental research of ENP environmental fate to the water characteristic in regions near the expected ENP emission sources. Under conditions favoring heteroaggregation in these regions, the fate of the ENPs can be readily predicted.
- Organisation(s)
- External organisation(s)
- Eidgenössische Technische Hochschule Zürich, Aix-Marseille Université, Bureau des Recherches Geologiques et Minieres (BRGM)
- Journal
- Science of the Total Environment
- Volume
- 535
- Pages
- 150–159
- No. of pages
- 10
- ISSN
- 0048-9697
- DOI
- https://doi.org/10.1016/j.scitotenv.2014.12.025
- Publication date
- 12-2015
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104023 Environmental chemistry, 104002 Analytical chemistry, 105906 Environmental geosciences, 210004 Nanomaterials
- Keywords
- ASJC Scopus subject areas
- Pollution, Waste Management and Disposal, Environmental Engineering, Environmental Chemistry
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/addressing-the-complexity-of-water-chemistry-in-environmental-fate-modeling-for-engineered-nanoparticles(f84503d2-dd71-4de8-b06a-952bb000020c).html