A Discrete Chloride Monohydrate
- Author(s)
- Mohammed S. Abdelbassit, Owen J. Curnow, Eugen Libowitzky, Ross O. Piltz, Matthew I. J. Polson
- Abstract
The solid-state structure of a discrete chloride monohydrate species, [Cl(H2O)]-, is reported for the first time. It was isolated as a salt of the tris(dipropylamino)cyclopropenium cation and has been structurally characterized by X-ray and neutron diffraction. Infrared (IR), far-infrared, and Raman spectroscopic studies were also carried out. Additionally, the D2O and HDO isotopomers were investigated. Of the six fundamental vibrational modes, only the out-of-plane bend ν3 was not observed as it forms an IR- and Raman-inactive local mode phonon.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- University of Canterbury, Australian Centre for Neutron Scattering
- Journal
- The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
- Volume
- 124
- Pages
- 9244-9251
- No. of pages
- 8
- ISSN
- 1089-5639
- DOI
- https://doi.org/10.1021/acs.jpca.0c07589
- Publication date
- 11-2020
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105113 Crystallography, 105116 Mineralogy, 104026 Spectroscopy
- Keywords
- ASJC Scopus subject areas
- Geochemistry and Petrology
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/f995e2a1-3e11-41b6-be19-83848ff2dd9a