β-Alaninium tetrafluoroborate
- Author(s)
- V. V. Ghazaryan, Michel Fleck, Aram M. Petrosyan
- Abstract
β-Alaninium tetrafluoroborate crystallizes in the monoclinic system (space group P2
1/n, Z = 4). The asymmetric unit contains one β-alaninium cation and one tetrafluoroborate anion, in which the fluorine atoms are disordered. All β-alaninium cations are connected with the symmetry related cations via an inversion center, thus forming dimeric centrosymmetric β-Ala
+···β-Ala
+ cations. The O···O distance (2.698(2) Å) in the dimeric cation is relatively long compared to known distances of previously reported salts with A
+···A
+ type dimeric cations. The infrared and Raman spectra are studied.
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- National Academy of Sciences of the Republic of Armenia
- Journal
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
- Volume
- 146
- Pages
- 214-220
- No. of pages
- 7
- ISSN
- 1386-1425
- DOI
- https://doi.org/10.1016/j.saa.2015.03.080
- Publication date
- 03-2015
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 104015 Organic chemistry, 104017 Physical chemistry, 105113 Crystallography
- Keywords
- ASJC Scopus subject areas
- Analytical Chemistry, Instrumentation, Atomic and Molecular Physics, and Optics, Spectroscopy
- Portal url
- https://ucrisportal.univie.ac.at/en/publications/alaninium-tetrafluoroborate(6b13df2f-1e90-4b3f-b0ed-5915784fd060).html