Tuning the performance of MgO for thermochemical energy storage by dehydration – From fundamentals to phase impurities

Author(s)
Danny Müller, Christian Knoll, G. Gravogl, Werner Artner, J. M. Welch, Elisabeth Eitenberger, Gernot Friedbacher, Manfred Schreiner, Michael Harasek, Klaudia Hradil, Andreas Werner, Ronald Miletich, Peter Weinberger
Abstract

Systematic variation of the dehydration temperature and time enables the preparation of highly reactive magnesium oxide for thermochemical energy storage purposes. The reactivity of the MgO, resulting from varying dehydration conditions has been studied by a comparative approach, including reactive surface area, particle morphology and reactivity towards rehydration. For the rehydration an in-situ powder X-Ray diffraction setup is used, allowing for continuous monitoring of Mg(OH)2 formation. The outcome of this investigation was subsequently applied to MgO from natural magnesites to assess the impact of impurities in the material on rehydration reactivity.

Organisation(s)
Department of Mineralogy and Crystallography
External organisation(s)
Technische Universität Wien, Akademie der bildenden Künste Wien
Journal
Applied Energy
Volume
253
No. of pages
11
ISSN
0306-2619
DOI
https://doi.org/10.1016/j.apenergy.2019.113562
Publication date
08-2019
Peer reviewed
Yes
Austrian Fields of Science 2012
105113 Crystallography, 104011 Materials chemistry
Keywords
ASJC Scopus subject areas
Building and Construction, Energy(all), Mechanical Engineering, Management, Monitoring, Policy and Law
Portal url
https://ucris.univie.ac.at/portal/en/publications/tuning-the-performance-of-mgo-for-thermochemical-energy-storage-by-dehydration--from-fundamentals-to-phase-impurities(5fadaa4d-e1f0-49fc-9dbb-769c2bdc66da).html