A 'sugar-coated' carbene precursor: A single crystal X-ray diffraction and NMR study
- Author(s)
- Michael Bobek, Gerald Giester, Hanspeter Kählig, Udo H. Brinker
- Abstract
For the first time, the inclusion complex of any diazirine with a cyclodextrin was studied by single crystal X-ray diffraction. This and 2D NMR spectroscopy were employed to elucidate the structure in both the solid state and solution. An opposite orientation of the guest inside the host molecule was revealed. Moreover, crystallization of the neat guest enabled the first X-ray diffraction of a dialkyl-substituted diazirine. (C) 2000 Published by Elsevier Science Ltd.
- Organisation(s)
- Department of Mineralogy and Crystallography, Department of Organic Chemistry
- External organisation(s)
- Universität Wien
- Journal
- Tetrahedron Letters
- Volume
- 41
- Pages
- 5663-5667
- No. of pages
- 5
- ISSN
- 0040-4039
- DOI
- https://doi.org/10.1016/S0040-4039(00)00938-2
- Publication date
- 2000
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 1040 Chemistry
- Portal url
- https://ucris.univie.ac.at/portal/en/publications/a-sugarcoated-carbene-precursor-a-single-crystal-xray-diffraction-and-nmr-study(4e68722b-a4bb-4cb0-8e57-cbfcf4851ca6).html