Nomenclature of the tourmaline-supergroup minerals
- Author(s)
- Darell J. Henry, M. Novák, Frank C: Hawthorne, Andreas Ertl, Barbara L. Dutrow, Pavel Uher, Federico Pezzotta
- Abstract
A nomenclature for tourmaline-supergroup minerals is based on chemical systematics using the generalized tourmaline structural formula: XY3Z6(T6O18)(BO3)3V3W, where the most common ions (or vacancy) at each site are X = Na1+, Ca2+, K1+, and vacancy; Y = Fe2+, Mg2+, Mn2+, Al3+, Li1+, Fe3+, and Cr3+; Z = Al3+, Fe3+, Mg2+, and Cr3+; T = Si4+, Al3+, and B3+; B = B3+; V = OH-1 and O-2; and W = OH-1, F-1, and O-2. Most compositional variability occurs at the X, Y, Z, W, and V sites. Tourmaline species are defined in accordance with the dominant-valency rule such that in a relevant site the dominant ion of the dominant valence state is used for the basis of nomenclature. Tourmaline can be divided into several groups and subgroups. The primary groups are based on occupancy of the X site, which yields alkali, calcic, or X-vacant groups. Because each of these groups involves cations (or vacancy) with a different charge, coupled substitutions are required to relate the compositions of the groups. Within each group, there are several subgroups related by heterovalent coupled substitu¬tions. If there is more than one tourmaline species within a subgroup, they are related by homovalent substitutions. Additionally, the following considerations are made. (1) In tourmaline-supergroup minerals dominated by either OH-1 or F-1 at the W site, the OH-1-dominant species is considered the reference root composition for that root name: e.g., dravite. (2) For a tourmaline composition that has most of the chemical characteristics of a root composition, but is dominated by other cations or anions at one or more sites, the mineral species is designated by the root name plus prefix modifiers, e.g., fluor-dravite. (3) If there are multiple prefixes, they should be arranged in the order occurring in the structural formula, e.g., "potassium-fluor-dravite".
- Organisation(s)
- Department of Mineralogy and Crystallography
- External organisation(s)
- Louisiana State University, Masaryk University, University of Manitoba, Comenius University Bratislava, University of Florence
- Journal
- American Mineralogist: an international journal of earth and planetary materials
- Volume
- 96
- Pages
- 895-913
- No. of pages
- 19
- ISSN
- 0003-004X
- Publication date
- 2011
- Peer reviewed
- Yes
- Austrian Fields of Science 2012
- 105116 Mineralogy
- Portal url
- https://ucris.univie.ac.at/portal/en/publications/nomenclature-of-the-tourmalinesupergroup-minerals(a133352f-a2a4-4edc-92d4-7e2f56efc764).html